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Special Issue Review

Perovskites in catalysis and electrocatalysis

Jonathan Hwang https://orcid.org/0000-0001-8257-921X, Reshma R. Rao https://orcid.org/0000-0002-6655-3105, Livia Giordano https://orcid.org/0000-0002-6879-9424, Yu Katayama https://orcid.org/0000-0002-7842-2938, Yang Yu https://orcid.org/0000-0001-9937-2338, and Yang Shao-Horn https://orcid.org/0000-0001-8714-2121 [email protected]
Science • 10 Nov 2017 • Vol 358, Issue 6364 • pp. 751-756 • DOI: 10.1126/science.aam7092
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Abstract

Catalysts for chemical and electrochemical reactions underpin many aspects of modern technology and industry, from energy storage and conversion to toxic emissions abatement to chemical and materials synthesis. This role necessitates the design of highly active, stable, yet earth-abundant heterogeneous catalysts. In this Review, we present the perovskite oxide family as a basis for developing such catalysts for (electro)chemical conversions spanning carbon, nitrogen, and oxygen chemistries. A framework for rationalizing activity trends and guiding perovskite oxide catalyst design is described, followed by illustrations of how a robust understanding of perovskite electronic structure provides fundamental insights into activity, stability, and mechanism in oxygen electrocatalysis. We conclude by outlining how these insights open experimental and computational opportunities to expand the compositional and chemical reaction space for next-generation perovskite catalysts.
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Volume 358 | Issue 6364
10 November 2017

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This work was supported in part by the Skoltech-MIT Center for Electrochemical Energy and Eni.

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Jonathan Hwang https://orcid.org/0000-0001-8257-921X
Department of Materials Science and Engineering, Massachusetts Institute of Technology (MIT), Cambridge, MA 02139, USA.
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Reshma R. Rao https://orcid.org/0000-0002-6655-3105
Department of Mechanical Engineering, MIT, Cambridge, MA 02139, USA.
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Livia Giordano https://orcid.org/0000-0002-6879-9424
Department of Mechanical Engineering, MIT, Cambridge, MA 02139, USA.
Department of Material Science, Università di Milano-Bicocca, Via Cozzi 55, 20136 Milano, Italy.
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Yu Katayama https://orcid.org/0000-0002-7842-2938
Research Laboratory of Electronics, MIT, Cambridge, MA 02139, USA.
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.
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Yang Yu https://orcid.org/0000-0001-9937-2338
Department of Materials Science and Engineering, Massachusetts Institute of Technology (MIT), Cambridge, MA 02139, USA.
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Yang Shao-Horn* https://orcid.org/0000-0001-8714-2121 [email protected]
Department of Materials Science and Engineering, Massachusetts Institute of Technology (MIT), Cambridge, MA 02139, USA.
Department of Mechanical Engineering, MIT, Cambridge, MA 02139, USA.
Research Laboratory of Electronics, MIT, Cambridge, MA 02139, USA.
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Notes

*Corresponding author. Email: [email protected]

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