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Enrichment of Heavy Metals and Organic Compounds in the Surface Microlayer of Narragansett Bay, Rhode Island

Science14 Apr 1972Vol 176, Issue 4031pp. 161-163DOI: 10.1126/science.176.4031.161

Abstract

Concentrations of lead, iron, nickel, copper, fatty acids, hydrocarbons, and chlorinated hydrocarbons are enriched from 1.5 to 50 times in the top 100 to 150 micrometers of Narragansett Bay water relative to the bulk water 20 centimeters below the surface. Trace metal enrichment was observed in the particulate and organic fractions but not in the inorganic fraction. If these substances are concentrated in films only a few molecular layers thick on the water surface, the actual enrichment factor in the films may be well over 104, resulting in extremely high localized pollutant concentrations in the surface microlayer.

References

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METCALFE, L.D., RAPID PREPARATION OF FATTY ACID ESTERS FROM LIPIDS FOR GAS CHROMATOGRAPHIC ANALYSIS, ANALYTICAL CHEMISTRY 38: 514 (1966).
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Science
Volume 176 | Issue 4031
14 April 1972

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Published in print: 14 April 1972

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Robert A. Duce
Graduate School of Oceanography, University of Rhode Island, Kingston
James G. Quinn
Graduate School of Oceanography, University of Rhode Island, Kingston
Charles E. Olney
Department of Food and Resource Chemistry, University of Rhode Island
Stephen R. Piotrowicz
Graduate School of Oceanography, University of Rhode lsland
Barbara J. Ray
Graduate School of Oceanography, University of Rhode lsland
Terry L. Wade
Graduate School of Oceanography, University of Rhode lsland

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