Covalent Polymers of Water
Abstract
A new covalent structural scheme for water polymers is proposed. The observed properties of "polywater" are related to the structures of the suggested homologous series of molecules. Mechanisms of formation are suggested.
References
ALLEN, L.C., A THEORY OF ANOMALOUS WATER, SCIENCE 167: 1443 (1970).
ANISIMOVA, V.I., PREPARATION OF STRUCTURALLY MODIFIED WATER IN QUARTZ CAPILLARIES, RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,USSR 41: 1282 (1967).
BARBARAS, G.D., THE PREPARATION OF THE HYDRIDES OF ZINC, CADMIUM, BERYLLIUM, MAGNESIUM AND LITHIUM BY THE USE OF LITHIUM ALUMINUM HYDRIDE, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 73: 4585 (1951).
BELLAMY, L.J., STUDIES OF MOLECULAR STRUCTURE AND SPECTRA OF ANOMALOUS WATER, CHEMISTRY & INDUSTRY: 686 (1969).
BOLANDER, R.W., CLUSTER STRUCTURE OF ANOMALOUS LIQUID WATER, NATURE 221: 1233 (1969).
DERYAGIN, B.V., BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR, DIVISION OF CHEMICAL SCIENCES: 2095 (1967).
DERYAGIN, B.V., DOKLADY AKADEMII NAUK SSSR 147: 402 (1962).
DERYAGIN, B.V., ALLOTROPY OF LIQUIDS WHEN THEIR VAPOUR IS CONDENSED IN QUARTZ CAPILLARIES, DOKLADY AKADEMII NAUK SSSR 165: 597 (1965).
DERYAGIN, B.V., IZVESTIYA AKADEMII NAUK SSSR, SERIYA KHIMICHESKAYA 10: 2178 (1967).
DERYAGUIN, B.V., PROCEEDINGS OF THE ACADEMY OF SCIENCES OF THE USSR. PHYSICAL CHEMISTRY SECTION 165: 807 (1965).
DERYAGIN, B.V., PRIRODA (MOSCOW) 4: 16 (1968).
DERYAGIN, B.V., SATURDAY REVIEW: 54 (6 9 1969).
DERYAGIN, B. V., JOINT PUBLICATIONS RESEARCH SERVICE 45 989 (1968).
DONOHUE, J, STRUCTURE OF POLYWATER, SCIENCE 166: 1000 (1969).
FEDYAKIN, N.N., COLLOID JOURNAL OF THE USSR 24: 425 (1962).
FEDYAKIN, N.N., MECHANISM UNDERLYING FORMATION OF WATER COLUMNS WITH SPECIAL PROPERTIES UPON CONDENSATION OF WATER VAPOUR IN BROAD FRESHLY DRAWN GLASS CAPILLARIES, DOKLADY AKADEMII NAUK SSSR 165: 878 (1965).
FEDYAKIN, N.N., KOLLOIDNYI ZHURNAL 24: 497 (1962).
FEDYAKIN, N.N., PROCEEDINGS OF THE ACADEMY OF SCIENCES OF THE USSR. PHYSICAL CHEMISTRY SECTION 165: 862 (1965).
HAMILTON, W.C., ELECTRONIC STRUCTURE OF DIBORANE, JOURNAL OF CHEMICAL PHYSICS 29: 460 (1958).
HAMILTON, W.C., A MOLECULAR ORBITAL TREATMENT OF DIBORANE AS A 4-CENTRE, 4-ELECTRON PROBLEM, PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES 235: 395 (1956).
HENNIKER, J.C., THE DEPTH OF THE SURFACE ZONE OF A LIQUID, REVIEWS OF MODERN PHYSICS 21: 322 (1949).
Hoekstra, P., Journal of Colloid and Interface Science, in press.
LIPPINCOTT, E.R., POLYWATER, SCIENCE 164: 1482 (1969).
Lipscomb, W. N., Boron Hydrides (1963).
Muetterties, E. L., The Chemistry of Boronand Its Compounds: 249 (1967).
MULLIKEN, R.S., *QUELQUES ASPECTS DE LA THEORIE DES ORBITALES MOLECULAIRES, JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE 46: 497 (1949).
MULLIKEN, R.S., *QUELQUES ASPECTS DE LA THEORIE DES ORBITALES MOLECULAIRES (SUITE ET FIN), JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE 46: 675 (1949).
ODONSKI, C.T., JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 79: 5634 (1957).
O'Konski, C. T., Encyclopedia of Polymer Science and Technology 9: 551 (1968).
ONSAGER, L, THE EFFECTS OF SHAPE ON THE INTERACTION OF COLLOIDAL PARTICLES, ANNALS OF THE NEW YORK ACADEMY OF SCIENCES 51: 627 (1949).
ONSAGER, L, PHYS REV 62: 558 (1942).
PAGE, T.F., POLYWATER . PROTON NUCLEAR MAGNETIC RESONANCE SPECTRUM, SCIENCE 167: 51 (1970).
PETSKO, G.A., PERSONAL COMMUNICATION.
PETSKO, G.A., PROTON MAGNETIC RESONANCE SPECTRUM OF POLYWATER, SCIENCE 167: 171 (1970).
PITZER, K.S., ELECTRON DEFICIENT MOLECULES .1. THE PRINCIPLES OF HYDROBORON STRUCTURES, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 67: 1126 (1945).
SNOW, A.I., THE STRUCTURE OF DIMETHYLBERYLLIUM, ACTA CRYSTALLOGRAPHICA 4: 348 (1951).
Verwey, E. J. W., Theory of the Stability of Lyophobic Colloids (1948).
WIBERG, E, ZEITSCHRIFT FUR NATURFORSCHUNG 66: 171 (1951).
WILLIS, E, ANOMALOUS WATER, NATURE 222: 159 (1969).
YAMAZAKI, M, ELECTRONIC STRUCTURE OF DIBORANE, JOURNAL OF CHEMICAL PHYSICS 27: 1401 (1957).
Get full access to this article
View all available purchase options and get full access to this article.
Already a Subscriber?Sign In
Information & Authors
Information
Published In
Science
Volume 168 | Issue 3935
29 May 1970
29 May 1970
Copyright
© 1970.
Submission history
Published in print: 29 May 1970
Authors
Metrics & Citations
Metrics
Article Usage
Altmetrics
Citations
Export citation
Select the format you want to export the citation of this publication.
Cited by
- Hydrogen-Bond Stereochemistry and "Anomalous Water", Science, 172, 3980, (231-242), (1971)./doi/10.1126/science.172.3980.231
Loading...
View Options
Get Access
Log in to view the full text
AAAS login provides access to Science for AAAS Members, and access to other journals in the Science family to users who have purchased individual subscriptions.
- Become a AAAS Member
- Activate your AAAS ID
- Purchase Access to Other Journals in the Science Family
- Account Help
Log in via OpenAthens.
Log in via Shibboleth.
More options
Purchase digital access to this article
Download and print this article for your personal scholarly, research, and educational use.
Buy a single issue of Science for just $15 USD.
View options
PDF format
Download this article as a PDF file
Download PDF