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Abstract

The refractive indices of polywater columns in glass capillaries have been rapidly and accurately measured with an interference microscope. Polywater has been detected by this method in both quartz and Vycor glass capillaries. A comparison of refractive index measurements with measurements of optical anisotropy indicates that polywater initially condenses with an ordered structure.

References

ANISIMOVA, V.I., PREPARATION OF STRUCTURALLY MODIFIED WATER IN QUARTZ CAPILLARIES, RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY,USSR 41: 1282 (1967).
Chamot, E. M., Handbook of Chemical Microscopy 1: 270 (1958).
DERYAGIN, B.V., THERMAL EXPANSION OF A STRUCTURAL MODIFICATION OF WATER IN QUARTZ CAPILLARIES, DOKLADY AKADEMII NAUK SSSR 170: 876 (1966).
DERYAGIN, B.V., SOVIET PHYSICS-DOKLADY 13: 763 (1969).
DERYAGIN, B.V., SOVIET PHYSICS-DOKLADY 13: 1030 (1969).
FEDAYKIN, N.N., DOKLADY AKADEMII NAUK SSSR 165: 878 (1965).
LIPPINCOTT, E.R., POLYWATER, SCIENCE 164: 1482 (1969).
WILLIS, E, ANOMALOUS WATER, NATURE 222: 159 (1969).
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Published In

Science
Volume 167 | Issue 3919
6 February 1970

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Published in print: 6 February 1970

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G. A. Castellion
American Cyanamid Company, Central Research Division, Stamford, Connecticut 06904
D. G. Grabar
American Cyanamid Company, Central Research Division, Stamford, Connecticut 06904
J. Hession
American Cyanamid Company, Central Research Division, Stamford, Connecticut 06904
H. Burkhard
American Cyanamid Company, Central Research Division, Stamford, Connecticut 06904

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  1. Hydrogen-Bond Stereochemistry and "Anomalous Water", Science, 172, 3980, (231-242), (1971)./doi/10.1126/science.172.3980.231
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  2. Polywater Discovered 30 Years Ago?, Science, 169, 3946, (705-705), (1970)./doi/10.1126/science.169.3946.705-b
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  3. Anomalous Water: Attempts at High-Pressure Synthesis, Science, 169, 3941, (175-176), (1970)./doi/10.1126/science.169.3941.175
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  4. Polywater Discovered 30 Years Ago?, Science, 169, 3946, (705-705), (1970)./doi/10.1126/science.169.3946.705.b
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