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Abstract

A structure for "polywater" is proposed. It consists of hydrogen-bonded clusters of water molecules lying at the vertices of rhombic dodecahedra. This structure contains features which are less unattractive than those which are part of several earlier models.

References

BELLAMY, L. J., CHEMISTRY & INDUSTRY: 686 (1969).
BOLANDER, R.W., CLUSTER STRUCTURE OF ANOMALOUS LIQUID WATER, NATURE 221: 1233 (1969).
CLARK, J.R., WATER MOLECULES IN HYDRATED ORGANIC CRYSTALS, REVIEWS OF PURE AND APPLIED CHEMISTRY 13: 50 (1963).
DARLOW, S.F., CRYSTAL STRUCTURE OF POTASSIUM HYDROGEN MALEATE, ACTA CRYSTALLOGRAPHICA 14: 1250 (1961).
DERYAGIN, B. V., PRIRODA 4 (1968).
DERYAGIN, B.V., JOINT PUBLICATIONS RESEARCH SERVICE 45 989 (1968).
ELLISON, R. D., ACTA CRYSTALLOGRAPHICA 19: 260 (1965).
FERGUSON, G, CHEMICAL COMMUNICATIONS: 162 (1968).
HAMILTON, W. C., ACTA CRYSTALLOGRAPHICA 16: 1209 (1963).
Kamb, B., Structural Chemistry and Biological Specificity: 507 (1966).
LEAR, J, SATURDAY REVIEW 52: 49 (1969).
LIPPINCOTT, E.R., POLYWATER, SCIENCE 164: 1482 (1969).
PAULING, L, THE STRUCTURE OF CHLORINE HYDRATE, PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA 38: 112 (1952).
PETERSON, S.W., STRUCTURE OF POTASSIUM HYDROGEN MALEATE BY NEUTRON DIFFRACTION, JOURNAL OF CHEMICAL PHYSICS 29: 948 (1958).
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Published In

Science
Volume 166 | Issue 3908
21 November 1969

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Published in print: 21 November 1969

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Jerry Donohue
Department of Chemistry and Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia 19104

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Cited by
  1. Hydrogen-Bond Stereochemistry and "Anomalous Water", Science, 172, 3980, (231-242), (1971)./doi/10.1126/science.172.3980.231
    Abstract
  2. Covalent Polymers of Water, Science, 168, 3935, (1089-1091), (1970)./doi/10.1126/science.168.3935.1089
    Abstract
  3. Polywater: Possibility of p-Electron Delocalization, Science, 168, 3930, (479-480), (1970)./doi/10.1126/science.168.3930.479
    Abstract
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