Advertisement

A 23,000-Year Record of Surface Water pH and PCO2 in the Western Equatorial Pacific Ocean

Science18 Apr 2003Vol 300, Issue 5618pp. 480-482DOI: 10.1126/science.1080796

Abstract

The oceans play a major role in defining atmospheric carbon dioxide (CO2) levels, and although the geographical distribution of CO2 uptake and release in the modern ocean is understood, little is known about past distributions. Boron isotope studies of planktonic foraminifera from the western equatorial Pacific show that this area was a strong source of CO2 to the atmosphere between approximately 13,800 and 15,600 years ago. This observation is most compatible with increased frequency of La Niña conditions during this interval. Hence, increased upwelling in the eastern equatorial Pacific may have played an important role in the rise in atmospheric CO2 during the last deglaciation.
Get full access to this article

View all available purchase options and get full access to this article.

Already a Subscriber?

References and Notes

1
W. S. Broecker, Progr. Oceanogr.2, 151 (1982).
2
D. M. Sigman, E. A. Boyle, Nature407, 859 (2000).
3
T. Takahashi et al., Deep Sea Res. II49, 1601 (2002).
4
A. Sanyal et al., Paleoceanography11, 513 (1996).
5
R. Zeebe, D. Wolf-Gladrow, CO2 in Seawater: Equilib- rium, Kinetics, Isotopes (Elsevier, Amsterdam, 2001).
6
W. H. Berger, J. S. Killingley, E. Vincent, Oceanol. Acta1, 203 (1978).
7
W. H. Berger, J. S. Killingley, Mar. Geol.45, 93 (1982).
8
M. Stuiver, P. J. Reimer, T. F. Braziunas, Radiocarbon40, 1127 (1998).
9
M. R. Palmer, P. N. Pearson, S. J. Cobb, Science282, 1468 (1998).
10
P. S. Dekens, D. W. Lea, D. K. Pak, H. J. Spero, Geochem. Geophys. Geosyst.3, 10.1029 (2002).
11
A. Indermuhle et al., Nature398, 121 (1999).
12
H. J. Smith et al., Nature400, 248 (1999).
13
J. W. Farrell, W. L. Press, Palaeoceanography4, 447 (1989).
14
S. J. Brown, H. Elderfield, Paleoceanography11, 543 (1996).
15
D. J. Mackey et al., Deep Sea Res. II44, 1951 (1997).
16
H. Y. Inoue, Y. Sugimura, Tellus44B, 1 (1992).
17
R. A. Feely et al., Deep Sea Res. II42, 365 (1995).
18
R. A. Feely et al., Deep Sea Res. II49, 2443 (2002).
19
M. H. Radenac, M. Rodier, Deep Sea Res. II43, 725 (1996).
20
J. S. S. Damste, W. I. C. Rijpstra, G. J. Reichart, Geochim. Cosmochim. Acta66, 2737 (2002).
21
L. Beaufort et al., Science293, 2440 (2001).
22
A. Koutavas, J. Lynch-Steiglitz, T. M. Marchitto, J. P. Sachs, Science297, 226 (2002).
23
L. Stott, C. Poulsen, S. Lund, R. Thunell, Science297, 222 (2002).
24
K. Visser, R. Thunnell, L. Stott. Nature421, 152 (2003).
25
F. Marcantonio et al., Earth Planet. Sci. Lett.184, 505 (2001).
26
L. C. Petersen, G. H. Haug, K. A. Hughen, U. Rohl, Science290, 1949 (2000).
27
P. M. Grootes, M. Stuiver, J. Geophys. Res.102, 26455 (1997).
28
H. J. Spero, D. W. Lea, Science296, 522 (2002).
30
P. Blanchon, J. Shaw, Geology23, 4 (1995).
31
This work was funded by the Natural Environment Research Council and the 6C program of the EC. We thank W. Berger for supplying us with samples from core ERDC-92; G. Bianchi for providing the oxygen and carbon isotope data; M. J. Cooper and R. N. Taylor for providing assistance with the boron analyses; and E. J. Rohling, J. G. Shepherd, P. A. Wilson, and two anonymous reviewers for their helpful comments.

Information & Authors

Information

Published In

Science
Volume 300 | Issue 5618
18 April 2003

Article versions

You are viewing the most recent version of this article.

Submission history

Received: 25 November 2002
Accepted: 18 March 2003
Published in print: 18 April 2003

Permissions

Request permissions for this article.

Authors

Affiliations

M. R. Palmer*
School of Ocean and Earth Sciences, Southampton Oceanography Centre, European Way, Southampton SO14 3ZH, UK.
P. N. Pearson
Department of Earth Sciences, Cardiff University, Main Building, Post Office Box 914, Cardiff CF10 3YE, UK.

Notes

* To whom correspondence should be addressed. E-mail: [email protected]

Metrics & Citations

Metrics

Article Usage
Altmetrics

Citations

Export citation

Select the format you want to export the citation of this publication.

Cited by
  1. Seasonal origin of the thermal maxima at the Holocene and the last interglacial, Nature, 589, 7843, (548-553), (2021).https://doi.org/10.1038/s41586-020-03155-x
    Crossref
  2. Evolution of paleo-climate and seawater pH from the late Permian to postindustrial periods recorded by boron isotopes and B/Ca in biogenic carbonates, Earth-Science Reviews, 215, (103546), (2021).https://doi.org/10.1016/j.earscirev.2021.103546
    Crossref
  3. Early deglacial CO2 release from the Sub-Antarctic Atlantic and Pacific oceans, Earth and Planetary Science Letters, 554, (116649), (2021).https://doi.org/10.1016/j.epsl.2020.116649
    Crossref
  4. The pH dependence of the isotopic composition of boron adsorbed on amorphous silica, Geochimica et Cosmochimica Acta, 308, (1-20), (2021).https://doi.org/10.1016/j.gca.2021.05.052
    Crossref
  5. Preindustrial to Modern Interdecadal Variability in Coral Reef pH, Science, 309, 5744, (2204-2207), (2021)./doi/10.1126/science.1113692
    Abstract
  6. Rapid Rise of Sea Level 19,000 Years Ago and Its Global Implications, Science, 304, 5674, (1141-1144), (2021)./doi/10.1126/science.1094449
    Abstract
  7. Bioerosion traces in the Great Barrier Reef over the past 10 to 30 kyr, Palaeogeography, Palaeoclimatology, Palaeoecology, 542, (109503), (2020).https://doi.org/10.1016/j.palaeo.2019.109503
    Crossref
  8. Late Quaternary coccolith weight variations in the northern South China Sea and their environmental controls, Marine Micropaleontology, 154, (101798), (2020).https://doi.org/10.1016/j.marmicro.2019.101798
    Crossref
  9. Calcification of planktonic foraminifer Pulleniatina obliquiloculata controlled by seawater temperature rather than ocean acidification, Global and Planetary Change, 193, (103256), (2020).https://doi.org/10.1016/j.gloplacha.2020.103256
    Crossref
  10. Deep‐Sea Oxygen Depletion and Ocean Carbon Sequestration During the Last Ice Age, Global Biogeochemical Cycles, 33, 3, (301-317), (2019).https://doi.org/10.1029/2018GB006049
    Crossref
Loading...

View Options

Get Access

Log in to view the full text

AAAS ID LOGIN

AAAS login provides access to Science for AAAS Members, and access to other journals in the Science family to users who have purchased individual subscriptions.

Log in via OpenAthens.
Log in via Shibboleth.
More options

Purchase digital access to this article

Download and print this article for your personal scholarly, research, and educational use.

Purchase this issue in print

Buy a single issue of Science for just $15 USD.

View options

PDF format

Download this article as a PDF file

Download PDF

Media

Figures

Multimedia

Tables

Share

Share

Share article link

Share on social media